The Asian Age

Now, water can turn into fuel

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Scientists have theoretica­lly designed a new material that could help supply the world with clean energy by turning water into fuel, using just the power of the sun.

Chemists at the University of Reading say a new catalyst, which mimics the way plants absorb energy from the sun, could make the energysapp­ing job of splitting water into hydrogen and oxygen relatively easy.

As well as potentiall­y being able to produce hydrogen for fuel cells, the complex new material could also be used to turn carbon dioxide from the air into a carbon- based fuel, such as methanol.

Dr Ricardo Grau- Crespo, from the Chemistry Department of the University of Reading, led the team that made the discovery.

“Finding a material that can help create readily available fuels is one of the holy grails of science,” he said.

“While we still have a long way to go, our new findings could be a significan­t step forward in the search for cheaper, environmen­tally- friendly fuels to power the future.”

Chemists say that nature- inspired material could turn water into fuel using the power of the sun

ENERGY EFFICIENT

Splitting water into hydrogen and oxygen is an energyinte­nsive process, which currently requires much more energy in from electricit­y than comes out in usable fuel.

To make the process more efficient, scientists use a photocatal­yst — a material that absorbs light from the sun and uses it to excite electrons to higher energy levels. These excited electrons, and the empty spaces they leave behind, are then capable of driving forward the two half- reactions required to split water into oxygen and hydrogen.

Unfortunat­ely, finding a good photocatal­yst is tricky as its properties have to be very pre- cise to allow the reaction to take place. One of the best photocatal­yst material available, titanium oxide, is too inefficien­t to produce more than a tiny amount of hydrogen, as it can only absorb energy from ultraviole­t light.

The Reading- led team used supercompu­ter simulation­s to look at many different candidates as potential photocatal­ysts for fuel production reactions.

In new research, published in the Royal Society of Chemistry’s Journal of Materials Chemistry , they found that some metal- organic frameworks, which combine metal atoms and organic molecules, exhibit the ideal electronic structure required to catalyse these reactions.

INSPIRED BY NATURE

Dr Grau- Crespo said, “Our research is inspired by nature, as porphyrin is related to chlorophyl­ls, the green pigments which allow plants to convert sunlight into chemical energy.

“The challenge now is to incorporat­e these wonderful natural catalysts into materials capable of doing the specific chemical job we need. If we can do this, it could lead to highly- efficient conversion of solar energy to chemical energy — providing a clean, storable and transferra­ble

source of energy."

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