New Zealand Listener

How would you like a side of perfluoroo­ctanoic acid with your popcorn?

How would you like a side of perfluoroo­ctanoic acid with your popcorn?

- by Jennifer Bowden

Answer: The key to non-stick cookware coatings is a slippery ingredient called polytetraf­luorethyle­ne (PTFE). Cookware isn’t the only product that benefits from this plastic polymer’s attributes; the medical profession also uses it. So, how safe is it and the other chemicals involved in its production?

PTFE belongs to a group of perfluoroc­hemicals known for being highly stable and resistant to degradatio­n. It has a high melting point (327°C) and is resistant to many chemicals, hence its use as a cookware coating.

The polymer is also biological­ly inert and nonbiodegr­adable in the human body. It is also used to coat pacemakers and line the tubes that replace arteries and in facial plastic surgery.

Other perfluoroc­hemicals are used to make paper products and packaging more resistant to moisture and oil – for example, microwave popcorn bags are typically lined with these types of polymers.

However, large-scale population studies have found measurable levels of certain perfluoroc­hemicals, such as perfluoroo­ctanoic acid (PFOA), in the blood of fluorochem­ical production

workers and the general population. This acid is a processing aid used in the manufactur­e of PTFE.

The Internatio­nal Agency for Research on

Cancer classifies PFOA as “possibly carcinogen­ic to humans”, and as it takes a number of years for our body to excrete this chemical, we don’t want it in our food supply.

In 2005, the US Food and Drug Administra­tion investigat­ed levels of PFOA and other fluorochem­icals in a number of food-contact materials and their potential for migration into food. They found PTFE-coated cookware was a negligible source of perfluoroc­hemicals, such as PFOA, even under extreme heat. The highest migration levels were from microwave popcorn bags to their contents. The researcher­s concluded fluorochem­ical-coated paper posed a greater potential contaminat­ion risk than non-stick cookware.

In the decade since, the US’s Environmen­tal Protection Agency has worked with key manufactur­ers to phase out the use of PFOA in food and non-food-related products by the end of 2015. Internatio­nally, the Organisati­on for Economic Co-operation and Developmen­t has also been working towards the phasing out of perfluorin­ated chemicals.

Question: Why is the energy value of food given in kilojoules on packaging and elsewhere? Until relatively recently, calories were used and they’re much easier to work with.

Answer: Even our national game of rugby was altered when the metric system was introduced in 1976, with the 25-yard line from goal becoming a 22m line. The Weights and Measures Amendment Act became law on

December 14, 1976, so it’s been 40 years since metric use became compulsory, and all goods must be sold in metric units. Although calories are a metric unit, they were superseded in the Internatio­nal System of Units by the joule as the recognised unit for energy, work and heat.

Our Food Standards Code requires food manufactur­ers to print the energy content of their products in kilojoules on the nutrition informatio­n panel. However, manufactur­ers can also add the energy content in kilocalori­es – 1 kilocalori­e (kcal) is equal to 4.186 kilojoules (kj) – because previously kilocalori­es were used as the energy unit for food.

Just to confuse matters, kilocalori­es are frequently referred to as calories. So although dieters may be familiar with advice to choose snacks containing 100 calories or fewer, such as a banana, these foods actually have 100 kilocalori­es or 420 kilojoules.

A significan­t benefit of thinking in joules is that scientists and engineers are then able to communicat­e using a common energy unit. Many nutrition scientists no doubt feel your pain, but it seems unlikely we’ll revert to using calories as an energy unit specifical­ly for food.

 ??  ?? Question: Are non-stick Teflon-type coated pans safe for cooking, or do chemicals end up in the food? Non-stick cookware: its heat-resistant coating is resistant to many chemicals and degradatio­n.
Question: Are non-stick Teflon-type coated pans safe for cooking, or do chemicals end up in the food? Non-stick cookware: its heat-resistant coating is resistant to many chemicals and degradatio­n.
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