Materials used by the world’s leading superyacht builders are not particularly specialised, or expensive, just used in vast amounts. The superyacht yards often deploy large quantities of Rockwool, for example, available from any DIY store or builder’s merchants. They cram it into overhead voids in large overlapping slabs.
They also use products we’re familiar with such as 3M’s Thinsulate, or the US-made Reflectix or EU-made Armaflex. Metal yachts, and even some composite ones, also use spray foam, much as you might find in your attic.