HUSBAND NO. 3

Another co-star, Pushing Tin’s Billy Bob Thornton, 63, eloped with Angelina at a Las Vegas wedding chapel in 2000, barely a month after they took their romance public in the wake of his split from Laura Dern. After making headlines for their unusual behavior — wearing vials of each other’s blood around their necks, making out on red carpets — they separated in 2002 and divorced in 2003. In 2018, he admitted he “never felt good enough” for her.