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3 honored for work on lithium-ion batteries

- By David Keyton and Jamey Keaten

STOCKHOLM — If you’re reading this on a cellphone or laptop computer, you might thank this year’s three winners of the Nobel Prize in chemistry for their work on lithiumion batteries.

The batteries developed by the British, American and Japanese winners are far more revolution­ary than just for on-the-go computing and calling. The breakthrou­ghs they achieved also made storing energy from renewable sources more feasible, opening up a whole new front in the fight against global warming.

“This is a highly charged story of tremendous potential,” quipped Olof Ramstrom of the Nobel committee for chemistry.

The prize announced Wednesday went to John Goodenough, 97, an American engineerin­g professor at the University of Texas; Stanley Whittingha­m, 77, a British-American chemistry professor at the State University of New York at Binghamton, and Akira Yoshino, 71, of Asahi Kasei Corp. and Meijo University in Japan.

The three scientists were honored for a transforma­tive technology that has affected anyone who uses cellphones, computers, pacemakers, electric cars and beyond.

“The heart of the phone is the rechargeab­le battery. The heart of the electric vehicle is the rechargeab­le battery. The success and failure of so many new technologi­es depends on the batteries,” said Alexej Jerschow, a chemist at New York University, whose research focuses on lithiumion battery diagnostic­s.

Goodenough, who is considered an intellectu­al giant of solid state chemistry and physics, is the oldest person to ever win a Nobel Prize — edging Arthur Ashkin, who was 96 when he was awarded the Nobel for physics last year.

Goodenough still works every day and said he is grateful he was not forced to retire at age 65. “So I’ve had an extra 33 years to keep working,” he told reporters in London.

Whittingha­m expressed hope the Nobel spotlight could give new impetus to efforts to meet the world’s ravenous — and growing — demands for energy.

“I am overcome with gratitude at receiving this award, and I honestly have so many people to thank; I don’t know where to begin,” he said in a statement.

“It is my hope that this recognitio­n will help to shine a much-needed light on the nation’s energy future.”

The three laureates each had unique breakthrou­ghs that cumulative­ly laid the foundation for the developmen­t of a commercial rechargeab­le battery to replace alkaline batteries containing lead, nickel or zinc that had their origins in the 19th century.

Lithium-ion batteries are the first truly portable and rechargeab­le batteries, and took more than a decade to develop. Their discovery drew upon the work of multiple scientists in the U.S., Japan and around the world.

The work had its roots in the oil crisis in the 1970s. Whittingha­m, who had researched supercondu­ctors at Stanford University, was hired by Exxon at a time when the petroleum giant was investing in research into other fields of energy amid concerns about depleting oil reserves.

Exxon gave researcher­s like him “the freedom to do pretty much what they wanted as long as it did not involve petroleum,” the Nobel committee said.

In his work, Whittingha­m harnessed the enormous tendency of lithium — the lightest metal — to give away its electrons to make a battery capable of generating just over two volts. Lithium, of all the elements, “is the one that most willingly releases electrons,” the committee said.

By 1980, building on Whittingha­m’s work, Goodenough had doubled the capacity of the battery to four volts by using cobalt oxide in the cathode — one of two electrodes, along with the anode, that make up the ends of a battery.

But that battery remained too explosive for general commercial use. That’s where Yoshino’s work in the 1980s came in. He eliminated the volatile pure lithium from the battery, and instead opted for lithium ions that are safer.

Yoshino substitute­d petroleum coke, a carbon material, in the battery’s anode. This step paved the way for the first lightweigh­t, safe, durable and rechargeab­le commercial batteries to be built and enter the market in 1991.

“We have gained access to a technical revolution,” said Sara Snogerup Linse of the Nobel committee for chemistry, alluding to the environmen­tal benefits of the discoverie­s. “The ability to store energy from renewable sources — the sun, the wind — opens up for sustainabl­e energy consumptio­n.”

Whittingha­m said he had no inkling that his work decades ago would have such a profound impact.

“We thought it would be nice and help in a few things, but never dreamed it would revolution­ize electronic­s and everything else,” he said. He called the prize “recognitio­n for the whole field.”

“Hundreds of people have worked on lithium-ion batteries, and I think people felt that they were being overlooked,” he said. “We’re hoping this will push the field further and faster.”

The trio will share a 9-million kronor ($918,000) cash award. Their gold medals and diplomas will be conferred in Stockholm on Dec. 10 — the anniversar­y of prize founder Alfred Nobel’s death in 1896.

The announceme­nt came on the third day of Nobel week.

On Tuesday, CanadianAm­erican James Peebles won the Nobel physics prize for his theoretica­l discoverie­s in cosmology together with Swiss scientists Michel Mayor and Didier Queloz, who were honored for finding an exoplanet — a planet outside our solar system — that orbits a solar-type star.

Americans William G. Kaelin Jr. and Gregg L. Semenza and Britain’s Peter J. Ratcliffe won the Nobel for advances in physiology or medicine on Monday. They were cited for their discoverie­s of ”how cells sense and adapt to oxygen availabili­ty.”

Two Nobel literature laureates are to be announced Thursday — one for 2018 and one for 2019 — because last year’s award was suspended after a sex-abuse scandal rocked the Swedish Academy. The coveted Nobel Peace Prize is Friday and the economics award will be announced on Monday.

Yoshino said he mistakenly thought there might be a long wait before the Nobel committee turned to his specialty. He broke the news to his wife, who was just as surprised as he.

“I only spoke to her briefly and said, ‘I got it,’ and she was so surprised that her knees almost gave way,” he told reporters in Tokyo.

The laureates said the field and its applicatio­ns are still a work in progress, and they want to keep at it.

Yoshino said lithium-ion batteries could have greater applicatio­n in the ocean and space, but that further research and developmen­t are needed to adapt them to other gadgets and purposes. “Lithium-ion itself is still full of unknowns,” he said.

The prize turned out to be a bit of a family affair among the researcher­s: Yoshino said he visits Goodenough nearly every year in Texas.

“For him, I’m like his son,” the Japanese laureate said. “He takes very good care of me.”

Goodenough, in his own way, seemed to return the favor, telling reporters in London that in all of his 97 years: “What am I most proud of? I don’t know, I would say all my friends.”

 ?? DANIEL LEAL-OLIVAS/GETTY-AFP ?? John Goodenough, 97, is now the oldest person to ever win a Nobel Prize.
DANIEL LEAL-OLIVAS/GETTY-AFP John Goodenough, 97, is now the oldest person to ever win a Nobel Prize.
 ?? TOMOHIRO OHSUMI/GETTY ?? Akria Yoshino says that “lithium-ion itself is still full of unknowns.”
TOMOHIRO OHSUMI/GETTY Akria Yoshino says that “lithium-ion itself is still full of unknowns.”
 ?? CHRISTOF STACHE/GETTY-AFP ?? Stanley Whittingha­m hopes the recognitio­n shines light on the future of energy.
CHRISTOF STACHE/GETTY-AFP Stanley Whittingha­m hopes the recognitio­n shines light on the future of energy.

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