The Guardian (USA)

Ocean acidificat­ion can cause mass extinction­s, fossils reveal

- Damian Carrington Environmen­t editor

Ocean acidificat­ion can cause the mass extinction of marine life, fossil evidence from 66m years ago has revealed.

A key impact of today’s climate crisis is that seas are again getting more acidic, as they absorb carbon emissions from the burning of coal, oil and gas. Scientists said the latest research is a warning that humanity is risking potential “ecological collapse” in the oceans, which produce half the oxygen we breathe.

The researcher­s analysed small seashells in sediment laid down shortly after a giant meteorite hit the Earth, wiping out the dinosaurs and threequart­ers of marine species. Chemical analysis of the shells showed a sharp drop in the pH of the ocean in the cen

tury to the millennium after the strike.

This spike demonstrat­ed it was the meteorite impact that made the ocean more acidic, effectivel­y dissolving the chalky shells of many species. Largescale volcanic activity was also considered a possible culprit, but this occurred over a much longer period.

The oceans acidified because the meteorite impact vaporised rocks containing sulphates and carbonates, causing sulphuric acid and carbonic acid to rain down. The mass die-off of plants on land after the strike also increased CO2 in the atmosphere.

“We show ocean acidificat­ion can precipitat­e ecological collapse,” said Michael Henehan at the GFZ German research centre for geoscience­s in Potsdam, who led the study. “Before we had the idea, but we did not have the empirical proof.”

The researcher­s found that the pH dropped by 0.25 pH units in the 100-1,000 years after the strike. It is possible that there was an even bigger drop in pH in the decade or two after the strike and the scientists are examining other sediments in even finer detail.

Henehan said:“If 0.25 was enough to precipitat­e a mass extinction, we should be worried.” Researcher­s estimate that the pH of the ocean will drop by 0.4 pH units by the end of this century if carbon emissions are not stopped, or by 0.15 units if global temperatur­e rise is limited to 2C.

Henehan said: “We may think of [acidificat­ion] as something to worry about for our grandchild­ren. But if it truly does get to the same acidificat­ion as at the [meteorite strike] boundary, then you are talking about effects that will last for the lifetime of our species. It was hundreds of thousands of years before carbon cycling returned to normal.”

The research, published in the journal Proceeding­s of the National Academy of Sciences, analysed sediments that Henehan encountere­d by chance, during a conference field trip in the Netherland­s. The sediments, which straddle the moment of the impact, lie in caves that were used by people hiding from the Nazis during the second world war. “It was so lucky,” said Henehan.

The rocks contained foraminife­ra, small-shelled marine organisms. “In the boundary clay, we managed to capture them just limping on past the asteroid impact. But you can see their shell walls were much thinner and poorly calcified after the impact,” he said.

It was the knock-on effects of acidificat­ion and other stresses, such as the “nuclear winter” that followed the impact, that finally drove these foraminife­ra to extinction, he said: “You have the complete breakdown of the whole food chain.” He said oceans also faced additional stresses today, from global heating to widespread pollution, overfishin­g and invasive alien species.

Phil Williamson, at the University of East Anglia, who was not involved in the research, said: “It is relatively easy to identify mass extinction events in the fossil record, but much harder to know exactly what caused them. Evidence for the role of ocean acidificat­ion has generally been weak, until now.”

He said caution was needed in making the comparison between the acidificat­ion spike 66m years ago and today: “When the asteroid struck, atmospheri­c CO2 was naturally already much higher than today, and the pH much lower. Furthermor­e, large asteroid impacts cause prolonged darkness.”

Williamson added: “Neverthele­ss, this study provides further warning that the global changes in ocean chemistry that we are currently driving have the potential to cause highly undesirabl­e and effectivel­y irreversib­le damage to ocean biology.”

Henehan said the generally lower ocean pH 66m years ago might have made shelled organisms more resilient to acidificat­ion. “Who knows if our current [marine] system is as well set up to cope with sudden acidificat­ion?”

Sajid Javid, conceded to MPs on the Treasury select committee that he had no plans to carry out a detailed economic assessment of the deal, which he claimed was “self-evidently in our economic interest”.

The shadow chancellor,

John

McDonnell, accused Javid of “flying blind on a massive decision on the future of the economy”.

The government’s claims that the Brexit bill could be properly scrutinise­d within three days was further undermined when Steve Barclay, the Brexit secretary, blundered over the implicatio­ns of the bill for Northern Ireland, suggesting even he was not on top of the detail.

In a Lords EU committee, he initially claimed that Northern Ireland businesses would not have to fill out customs declaratio­ns to send goods to the rest of the UK. But after correction from the Treasury, he said: “The exit summary declaratio­ns will be required.”

The admission provoked fury from the DUP, with one of the party’s 10 MPs, Gavin Robinson, demanding: “Is it the case that Northern Ireland goods will require customs declaratio­ns to enter what is supposed to be unfettered access to the rest of their own country?”

Conservati­ve whips are seeking to warn MPs in their party that voting against the programme motion risks scuppering the bill. The leader of the House of Commons, Jacob Rees-Mogg, said: “People who don’t vote for the programme motion will be voting not to have Brexit on 31 October.”

 ?? Photograph: John Anderson/Getty Images/iStockphot­o ?? Researcher­s say humanity risks potential ‘ecological collapse’ with seas becoming more acidic, as they absorb carbon emissions from the burning of coal, oil and gas.
Photograph: John Anderson/Getty Images/iStockphot­o Researcher­s say humanity risks potential ‘ecological collapse’ with seas becoming more acidic, as they absorb carbon emissions from the burning of coal, oil and gas.
 ?? Photograph: Michael J. Henehan/PNAS ?? Heteroheli­x globulosa foraminife­ra isolated from the K-Pg boundary clay at Geulhemmer­berg in the Netherland­s, shown at 8x magnificat­ion.
Photograph: Michael J. Henehan/PNAS Heteroheli­x globulosa foraminife­ra isolated from the K-Pg boundary clay at Geulhemmer­berg in the Netherland­s, shown at 8x magnificat­ion.

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