The Mercury News

Study says emissions adding acidity to area ocean waters.

Study: Winds transport emissions from hubs, likely making waters unfavorabl­e for many sea creatures

- By Priyanka Runwal prunwal@bayareanew­sgroup.com

Carbon dioxide, one of the main greenhouse gases linked to climate change, is not just a global problem, but a local one too, according to a recent study.

Scientists from the Monterey Bay Aquarium Research Institute (MBARI) report that CO2 emissions from Silicon Valley and Salinas Valley are blowing over to Monterey Bay, a region renowned for its rich marine life. They suspect this CO2 will get absorbed by the ocean, making the waters more acidic and unfavorabl­e for many sea creatures.

“This is a first-of-its-kind study to talk about CO2 from urban sources affecting acidificat­ion in coastal waters,” said Richard Feely, a chemical oceanograp­her with the National Oceanic and Atmospheri­c Administra­tion, who wasn’t involved in the research. “One might expect to see the same thing occur along the East Coast and places where there is high industrial activity near the coast.”

In urban hotspots, local emissions from transporta­tion or large industries create CO2 “domes.” This localized CO2 con

centration can hover over cities during early mornings, increasing urban air temperatur­es and affecting human health.

In the case of coastal urban hubs, land breezes can transport these CO2 domes offshore. This process is especially important during winters, when seaward-flowing winds predominat­e and are stronger. In winters, water is warmer than land, and this temperatur­e difference drives winds from land to sea.

At research stations in Monterey Bay, MBARI scientists began noticing high values of CO2 in the air between 2013 and 2018. Expected to range around 400 parts per million, air CO2 levels in Monterey Bay peaked at 450 on many occasions.

“At first they looked like randomly spaced peaks,” said lead researcher Devon Northcott. “But if you looked closely they seemed to align early in the morning, and more than that, they align with when they’re coming off the land.”

This was their first clue alluding to land-based pollution.

In the early days of making air and ocean CO2 measuremen­ts, MBARI scientists used sensors anchored to research ships. They associated high air CO2 levels to pollution from the ship. “We discarded those high values,” said Francisco Chavez, biological oceanograp­her at MBARI.

But in the past five years, they made measuremen­ts from sensors fitted on fixed moorings and a self-driving surface-water robot. The moorings are located at three locations near Monterey’s coast, and the robot journeys back and forth from Moss Landing to 31 miles into the sea, collecting data every hour.

“What was most surprising was the consistenc­y (in elevated air CO2 values) that we observed,” Chavez said. “We saw it over many days in the winter, and over many winters.”

Simultaneo­us measuremen­ts of wind direction and speed allowed his team to track the location of CO2’s origin. Also, based on wind flow, they figured that elevated CO2 air rarely travels beyond 60 miles offshore.

“These (CO2 emissions) were coming from Hecker Pass, which sort of connects us to Silicon Valley, and from the Salinas Valley,” Chavez said. His team considers human activities in the areas, as well as night-time CO2 respiratio­n from crops as possible contributo­rs.

In addition to global CO2, the ocean now has localized CO2 added to its absorption budget. But how much does this additional pollution amount to?

Researcher­s estimate a 20 percent increase in CO2 entering worldwide coastal waters. This is assuming that the process seen in Monterey Bay occurs similarly along all coasts.

“Twenty percent is really significan­t and important,” Feely said.

CO2 enhancemen­ts can make ocean water more acidic. And this is bad news for shelled ocean creatures like pteropods, which are microscopi­c marine snails devoured by salmon, as well as mussels and sea urchins. The acidity dissolves their shells.

Feely, however, cautions that these are early estimates. “They need to be substantia­ted with measuremen­ts in other coastal areas,” he said.

MBARI’s research team hopes for the same. They’d like to see scientists in other parts of the world make similar measuremen­ts. “We want to know if the same processes occur all over the world,” Chavez said. And not just for CO2, but other greenhouse gases like nitrous oxide too, he reckons.

Scott Doney, an oceanograp­her at the University of Virginia who wasn’t involved in the study, envisions further opportunit­ies for inquiry. “What I’d like to see moving forward is trying to figure out what the sources are,” he said. This would mean “dissecting” the CO2 dome and understand­ing the exact contributi­on of agricultur­e, transporta­tion or industries.

High-resolution data from satellites like NASA’s Orbiting Carbon Observator­y or isotopic fingerprin­ts of greenhouse gases may provide answers.

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 ?? COURTESY OF THE MONTEREY BAY AQUARIUM RESEARCH INSTITUTE ?? Wave Gliders like this one provide mobile platforms for measuring carbon dioxide in the air and waters of Monterey Bay.
COURTESY OF THE MONTEREY BAY AQUARIUM RESEARCH INSTITUTE Wave Gliders like this one provide mobile platforms for measuring carbon dioxide in the air and waters of Monterey Bay.

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