Montreal Gazette

INTEREST IN ELECTRICIT­Y SPARKED DISCOVERIE­S

Michael Faraday’s pioneering work helped change the course of history

- JOE SCHWARCZ The Right Chemistry joe.schwarcz@mcgill.ca Joe Schwarcz is director of McGill University’s Office for Science & Society (mcgill.ca/oss). He hosts The Dr. Joe Show on CJAD Radio 800 AM every Sunday from 3 to 4 p.m.

For anyone in the business of science communicat­ion, the Royal Institutio­n of Great Britain is a holy place. Founded in London in 1799 by the leading British scientists of the era, the institutio­n aimed to promote scientific education and research with an emphasis on public lectures focusing on the applicatio­n of science to everyday life. Perhaps the most famous lecturer to grace the institutio­n’s hallowed amphitheat­re was Michael Faraday, who enthralled audiences in the mid-19th century with lectures based on his numerous discoverie­s.

Before Faraday, electricit­y was essentiall­y a curiosity. The ancient Greeks were undoubtedl­y amazed when they accidental­ly discovered static electricit­y by noting that rubbing a piece of amber with a cat’s fur allowed it to attract feathers. They gave us the word electricit­y, deriving from the Greek “electron” for amber.

Benjamin Franklin with his famous kite experiment showed that lightning was a form of electricit­y, and in 1800, Alessandro Volta generated electricit­y by chemical action. His “voltaic pile” consisted of a pile of alternatin­g zinc and silver discs separated by pieces of cardboard soaked in salt water. A wire connecting the bottom zinc disc to the top silver disc produced sparks.

Volta’s invention had no immediate practical applicatio­n but did prove to have entertainm­ent value. Countryman Giovanni Aldini travelled around Europe sparking interest in electricit­y by “animating ” corpses with electric shocks. Young Mary Shelley witnessed one of these demonstrat­ions, which is thought to have implanted the idea that eventually blossomed into one of the most famous science fiction stories of all time, Frankenste­in.

Sir Humphry Davy, Michael Faraday’s mentor, put electricit­y to practical use, managing to isolate the element sodium for the first time by attaching the leads of a voltaic pile to two electrodes immersed in a salt solution. The positively charged sodium ions were attracted to the negative electrode where they picked up electrons to form neutral sodium atoms. Davy went on to isolate potassium, calcium, strontium, barium, magnesium, boron, chlorine and iodine through “electrolys­is.” Davy’s work ignited Faraday’s curiosity about electricit­y eventually leading to his major discovery that placing a conductor in a changing magnetic field produces a current in the conductor. This was the key to Faraday’s conceiving the electric motor, transforme­r and generator, inventions that changed the course of history.

Faraday’s interests encompasse­d more than just electricit­y. Sitting on a shelf in the Faraday Museum in the basement of the Royal Institutio­n of Great Britain is a small vial labelled “bicarburet of hydrogen,” a liquid that Faraday had isolated from of all things, whale oil! Today we know the colourless, sweetsmell­ing liquid as benzene, one of the world’s most important industrial chemicals, used in the production of plastics, pesticides, detergents, rubbers, drugs and explosives.

In the early 19th century, whale oil was used for lighting, either by directly burning it in lamps or by subjecting it to heat in a furnace to yield a gas that could be compressed to a transporta­ble liquid for later combustion. Particular­ly favoured was the oil from the nose of the sperm whale because it burned with less odour and smoke than other fuels. The popularity of whale oil took a toll on whales and would probably have forced the creatures into extinction had the clean-burning kerosene lamp not been invented in 1857. Kerosene was distilled from petroleum and was cheaper, did not spoil like animal fats, and burned cleaner. Eventually, benzene would also be found to be a component of petroleum from where it was isolated by fractional distillati­on for use as a solvent in the printing, leatherwor­king, metal degreasing, paint stripping and particular­ly rubber manufactur­ing industries. It was even used as an aftershave lotion because of its pleasant smell.

Since benzene was found to dissolve caffeine readily, it was the solvent used in the original process to decaffeina­te coffee beans. That was the invention of German coffee merchant Ludwig Roselius, back in 1905. Although advertised as “always harmless, always wholesome,” the decaffeina­ted coffee had traces of benzene. It seems Roselius was either not concerned with, or was unaware of the toxicity of benzene. By the time that he introduced his process, there had been reports of deaths among workers in tire factories where benzene was widely used because of its ability to dissolve rubber. Years later, benzene was found to cause leukemia and still represents an occupation­al hazard in the rubber and plastic manufactur­ing industries.

Lost in the accolades heaped on Michael Faraday for his great discoverie­s, is his campaign against pseudo-science, which was rampant at the time. Mediums were commonly using trickery during seances to convince the gullible of the presence of spirits and Faraday felt it was his duty to unmask these deceptions through public lectures. Were he with us today, he would be dismayed with the plethora of pseudo-science permeating the internet but would surely be thrilled by the wonders that his experiment­s in electricit­y germinated.

 ?? SERGEI GAPON/AFP/GETTY IMAGES ?? Oleg Melnik, wearing a wire helmet, getting electrical discharges of Tesla coil inside a Faraday cage at the Elemento Science Museum in Minsk in 2016. The Faraday cage blocks electromag­netic fields and was named for Michael Faraday, who invented it in the 19th century.
SERGEI GAPON/AFP/GETTY IMAGES Oleg Melnik, wearing a wire helmet, getting electrical discharges of Tesla coil inside a Faraday cage at the Elemento Science Museum in Minsk in 2016. The Faraday cage blocks electromag­netic fields and was named for Michael Faraday, who invented it in the 19th century.
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