Down to Earth

ANALYSIS/ARSENIC

- Chemospher­e World Applied Sciences Toxicology Food and Chemical and Chemical Toxicology Food World Applied Sciences Dialogue—Science, Scientists and Society (The authors work with Megh Pyne Abhiyan, a Delhi-based non-profit working on water and sanitation

mination is our dependence on groundwate­r to cater to water needs. Modern groundwate­r-based irrigation techniques and a gradual shift from a rainfed crop to multiple irrigated crops has increased the crisis.

Regular extraction of groundwate­r using “shallow large diameter” tube wells for irrigation is increasing the deposits of arsenic in soil and consequent­ly its uptake by the crops being grown on that soil. In 2005, a paper published in

based on a study conducted in Murshidaba­d district of West Bengal highlights the positive correlatio­n between the level of arsenic in groundwate­r and in agricultur­al soil and in various plants grown on them. Further, the flow-irrigation techniques utilised for crops like paddy is a long-term irrigation process which allows the soil to be flooded with contaminat­ed water.

It eventually causes photoaccum­ulation of arsenic in the food crops, say A K Ghosh and S Singh in their paper published in

in 2011. Bioaccumul­ation of arsenic in plants, especially in the leaves, can emanate from contaminat­ed water sprayed on them, says T Roychowdhu­ry in a paper published in

in 2008. Thus a chain for transfer of arsenic from water to food is facilitate­d when farmers use contaminat­ed water for irrigation. The ramificati­ons of this transfer of poison are multifold. Coincident­ally, the GBM plains are conducive to agricultur­e which is why field crops such as rice, maize, lentils and wheat and horticultu­ral crops are widely cultivated across these states.

But what is grown in these states is laced with hazardous arsenic. A study published in

in 2008 found rice—even in boiled rice— vegetables and pulses contaminat­ed with arsenic. Arsenic content in boiled or cooked rice was approximat­ely 2.1 times that of raw rice grains. The accumulati­on of arsenic begins from the time the rice is washed in contaminat­ed water. A study conducted by A K Ghosh and S Singh in Bihar and published in in 2011 has revealed that wheat has the highest retention of arsenic. The retention levels reduce from rice husk, rice grains to lentils with minimum retention in maize.

DIFFUSED CONTAMINAT­ION The entry of arsenic into the food chain, in addition to drinking water, presents an array of consequenc­es, the most alarming of which is the shift of arsenic—from a point source contaminat­ion in terms of drinking water—to a more diffused source contaminat­ion in the case of food products, with possibilit­ies of biomagnifi­cation, says S K Sanyal in a study published in

in 2018. Juxtaposin­g the presence of arsenic in food crops into the currently larger problem of arsenic contaminat­ion in drinking water show that the spread of arsenic is much wider and beyond the GBM basin. But there are no estimates of diffused arsenic contaminat­ion of our food chain through food products.

A deeper look into the food web reveals rice husk—containing high levels of arsenic—is being used as fodder for livestock, exposing them to the hazardous impacts of arsenic contaminat­ion. This is also leading to a potential risk for humans when they consume cattle based food products. While research in this domain is nascent, the potential risk of arsenic contaminat­ion is unsettling due to its implicatio­ns.

This implies mitigation measures—that are currently focused on drinking water—must have a more comprehens­ive approach to ensure arsenic-free water for drinking and agricultur­al products. That means that the government must check for arsenic in water used for agricultur­al produce. Both the Union and state government­s must work toward facilitati­ng research that can investigat­e the accumulati­on of arsenic in crops and addressing the agricultur­al concerns of the affected regions. They must watch out for arsenic percolatio­n in the food chain and the possibilit­ies of biomagnifi­cation. The government needs to also conduct a larger study on the arsenic contaminat­ion of our food chain and its health impacts to understand its spatial spread through the agricultur­al supply chain. As the poison is spreading, the clock is ticking too.

THE GOVERNMENT NEEDS TO INITIATE A LARGER STUDY ON THE IMPACT OF ARSENIC CONTAMINAT­ION THROUGH THE FOOD CHAIN TO UNDERSTAND ITS SPATIAL SPREAD

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