BBC Science Focus

ELECTRIC VEHICLES: WHAT CAN WE DO WITH THE GROWING NUMBER OF DEAD BATTERIES?

What will happen to the batteries when the first generation of electric vehicles reach the end of their lifespans in around a decade? Are they bound for the scrapheap, or can they be salvaged?

- By ROB BANINO Rob is a freelance science and technology journalist and editor.

Combustion-engine vehicles are viewed as enemies of the environmen­t and it’s easy to see why. By burning fossil fuels, every motorcycle, car, van and lorry adds to air pollution and contribute­s to climate change. It’s why government­s are encouragin­g drivers to switch to more environmen­tally friendly electric vehicles

(EVs). But while combustion-engine vehicles are an enemy in terms of emissions, they’re currently more of an ally when it comes to recycling.

The lead-acid batteries found in combustion­engine cars are easily and widely recycled, says Dr Daniel Reed, a lecturer in materials chemistry at the University of Birmingham. “Lead-acid batteries are the most recycled consumer product globally. [The technology is] mature and standardis­ed so it doesn’t matter who makes your battery or which car you own because the battery conforms to certain regulatory specificat­ions.”

The simplicity of lead-acid batteries also helps. They contain relatively few materials (lead for the electrodes, sulphuric acid for the electrolyt­e, and polypropyl­ene to encase everything), each of which can be easily separated and sold.

The lithium-ion batteries used in EVs are almost the exact opposite.

“In a lithium-ion battery, you’ve got about 10 different components that are interspers­ed as tiny composite materials, as well as fluorinate­d polymers, fluorinate­d electrolyt­es and fluorinate­d solvents, all which are a complete nightmare to separate,” says Prof Andrew Abbott, a physical chemist at the University of Leicester.

Many of those materials are toxic and some are pyrophoric, so may ignite if they come into contact with air, which makes breaking EV batteries down a complicate­d and costly process.

The other issue is that a lot of the materials in lithium-ion batteries are ‘critical metals’ (rare-earths, lithium and cobalt, for example), which are vital for making the switch to clean-energy technology but are found in just a few countries. So, the only way to ensure a lasting supply is to recover them from the products they’re used to make.

It therefore seems as if we’re facing further problems by switching to EVs. But it’s not all bad news.

First, EV batteries can be reused. Once they reach a point where they’re no longer able to power a vehicle, they can have a second life as storage devices for energy generated from renewable sources.

Second, it is possible to recycle EV batteries, it’s just complicate­d and, for the time being, not cost effective. But that’s set to change.

Due to improving battery performanc­e and measures like carbon taxes, it’s estimated we’ll reach price parity for combustion-engine vehicles and EVs by 2023. “[At that point] we’ll see a big change in terms of adoption,” says Abbott. “The lifetime of the batteries in these vehicles is estimated to be in excess of 10 years. So, in around 15 years the UK will probably be at a point where it has about half a million EVs a year that need recycling.”

By then, the market for EV batteries is expected to be 10 times the size of the current lead-acid battery market (based on the greater size of EV batteries and number of materials needed to make them, along with the declining number of combustion engine vehicles on the road), so there’ll be plenty of incentive to find more cost-effective methods of recycling EV batteries in the intervenin­g years. But while it’s

“There’s a need for a degree of legislatio­n to compel manufactur­ers to make sure these batteries are recycled”

in the interests of the manufactur­ers to ensure a supply of the necessary raw materials, it’s going to take more than just market forces to fully address this issue.

“There’s a need for a degree of legislatio­n to compel manufactur­ers to make sure these batteries are recycled. The European Union has brought in legislatio­n, which I believe the UK has copied,” says Reed, while acknowledg­ing that any legislatio­n can’t be too heavy-handed. “There needs to be freedom to innovate on recycling as well as battery manufactur­e. But the onus needs to be on recycling and recovering materials.”

Innovation on battery manufactur­e is vital because the complexity and variety of designs is arguably the major obstacle to recycling. Part of the problem is the technology is still emerging – new battery designs are continuall­y appearing, and committing to the wrong one could be disastrous for a battery or car manufactur­er.

A simpler, standardis­ed EV battery that’s safe, easy and cheap to separate into its component parts is the solution everyone’s looking for; in other words, the EV battery equivalent of the lead-acid battery. But it’s worth rememberin­g we’ve only had lithium-ion batteries since the 1980s. Lead-acid batteries appeared around 1860 and it wasn’t until the 1970s that the design for motor vehicles was standardis­ed.

“Standardis­ation will come in to some extent, but it’s a chicken-and-egg situation,” says Abbott. “[Recycling EV batteries] is a known problem and there are known solutions for it. It’s just ramping production and recycling up at the same rate and marrying the two together.”

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 ??  ?? A technician at a recycling factory checks for possible remaining voltage in a burned-out lithium-ion battery
A technician at a recycling factory checks for possible remaining voltage in a burned-out lithium-ion battery
 ??  ?? A used lithium-ion battery is opened up prior to being dismantled at a recycling factory in Germany
A used lithium-ion battery is opened up prior to being dismantled at a recycling factory in Germany

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