Dayton Daily News

What you need to know about PFAS in city water

Here are questions, answers about the chemicals.

- By Will Garbe Staff Writer

Dayton’s water is safe to drink by federal guidelines, city officials say, but it does contain some PFAS — chemicals believed to cause health problems.

The Dayton Daily News Path Forward project digs into solutions for the most pressing issues facing the community, including protecting the region’s drinking water that serves more than 400,000 people in Montgomery County.

That’s why we examined scientific research, public records, lawsuits and other sources to find out what’s really going on.

Here are answers to some of the most common questions about the chemicals.

What are PFAS?

PFAS stands for per- and polyfluoro­alkyl substances. These are human-produced chemical compounds containing fluorine and carbon atoms.

About 5,000 different types of PFAS exist. This article focuses on two forms known as perfluoros­ulfonates, or PFOS, and perfluoroc­arboxylic, or PFOA.

These PFAS resist heat, stains, grease, oil and water. The substances have been used in carpet and waterproof clothing treatments, nonstick coatings on pans, popcorn bags, cardboard packaging, firefighti­ng foam and other items.

PFAS are extremely persistent and can travel long distances. Studies show certain PFAS have been found in bald eagles, walrus, narwhals, beluga whales and polar bears. They can move up the food chain into fish and other animals. When humans consume contaminat­ed fish or shellfish, we consume the PFAS inside them, too.

Another way for PFAS to enter the human body is through contaminat­ed water.

Some people can be exposed to PFAS through their jobs, such as firefighti­ng or manufactur­ing. And the U.S. Centers for Disease Control and Prevention said certain food packages like popcorn bags, fast food containers and pizza boxes contained PFAS until recently.

Why are PFAS found in Dayton’s water?

PFAS can be used in a foam to extinguish fires involving fuel. The foam is sprayed on the fire and coats it to block oxygen feeding the fire.

Firefighte­rs trained for decades with the foam in at least two sites in our region for decades: Wright-Patterson Air Force Base and the Dayton Fire Training Center. Both of these locations are located above the Great Miami Buried Valley Aquifer, the source for the region’s drinking water.

The city of Dayton and state of Ohio have sued PFAS manufactur­ers.

The state’s lawsuit alleges the foam “releases these toxic chemicals directly into the environmen­t in a manner enabling them to seep freely into the groundwate­r — potentiall­y contaminat­ing drinking water supplies — and travel long distances to cause further, widespread environmen­tal contaminat­ion.”

“A single firefighti­ng event or training exercise may result in the release of thousands of gallons of foam solution,” Ohio’s complaint says. Dayton’s complaint says plumes of PFAS “can persist in undergroun­d aquifers for many decades. Once the plume reaches the well, it continues to contaminat­e the water drawn from that well.”

What are the health concerns?

Most people in the U.S. and other industrial­ized countries have measurable amounts of PFAS in their blood, according to the CDC, and at much lower levels in urine, breast milk and umbilical cord blood.

The chemicals are considered “emerging contaminan­ts” by the U.S. Environmen­tal Protection Agency, meaning they are chemicals characteri­zed by a perceived, potential or real threat to human health or the environmen­t, or by a lack of published health standards.

Dayton’s lawsuit alleges PFOA exposure can lead to “kidney and testicular cancer, thyroid disease, high cholestero­l, ulcerative colitis, liver damage, and pregnancy-induced hypertensi­on.” The complaint alleges PFOS exposure can lead to “immune system effects, changes in liver enzymes and thyroid hormones, low birth-weight, high uric acid, and high cholestero­l.”

Can I still breastfeed if I drink Dayton’s water?

Newborns can be exposed to PFAS through breast milk, but the CDC recommends nursing mothers continue to breastfeed their babies, because “the advantages of breastfeed­ing continue to greatly outweigh the potential risks in nearly every circumstan­ce.”

The CDC says older children might be exposed to PFAS through food and water, similar to adults. Younger children could be exposed through carpet cleaners and similar products, largely due to time spent lying and crawling on floors.

What does the manufactur­er say about the chemical?

In the 1940s, the 3M Co. began to experiment with a process to create key components of PFAS, the Ohio Attorney General’s Office alleges in its Lucas County Common Pleas Court filings.

3M says it started making firefighti­ng foam in 1963 and stopped in 2000.

PFAS are “top of mind” for 3M, the company’s top leader said last week while pushing back on claims the substances are harmful.

“The scientific evidence does not show that PFAS cause harm to people at past or current exposure levels,” 3M Chief Executive Mike Roman said Thursday during a company earnings call.

The company was the only foam manufactur­er that used PFOS, according to both the city and Ohio’s lawsuits. The other foam manufactur­ers used PFOA.

The highest levels of contaminat­ion in Dayton’s water are PFOS, according to Ohio Environmen­tal Protection Agency documents.

How much PFAS in water is considered dangerous?

The U.S. EPA currently doesn’t regulate PFAS but its understand­ing of the substance has evolved over time.

In 2009, it issued a health advisory that said “action should be taken to reduce exposure” to drinking water containing levels of PFOA exceeding 400 parts per trillion and PFOS exceeding 200 parts per trillion.

In 2016, the U.S. EPA said drinking water concentrat­ions for PFOA and PFOS, either singly or combined, should not exceed 70 parts per trillion.

These advisories aren’t enforceabl­e. As the Dayton Daily News has previously reported, other states have set their own levels. Michigan officials set a screening level of 9 parts per trillion for PFOA and 8 parts per trillion for PFOS.

A 2018 report from the CDC proposed health thresholds about 10 times lower than the U.S. EPA’s health threshold.

How much PFOS and PFOA are in Dayton’s water?

Earlier this year, the Dayton Daily News obtained a map showing PFOS and PFOA levels in groundwate­r monitoring wells. The map is from March and April 2018. It says Dayton measured PFOS at 1,500 parts per trillion near the Dayton Fire Training Center, and PFOA at about 79 parts per trillion near Huffman Dam. Certain wells have been turned off at both sites.

“The source of contaminat­ion at both well fields is separate and distinct, while the contaminat­ion is the same,” says an April 2018 memorandum of understand­ing between Dayton and Montgomery County.

The Dayton Daily News recently reported that PFAS is still measured in water leaving the Ottawa Treatment Plant — one of Dayton’s two drinking water treatment plants — even though the contaminat­ed wells have been turned off.

Earlier this month the newspaper reported Dayton tested water leaving the Ottawa plant in September 2018 and found PFOA and PFOS combined at nearly 19 parts per trillion. That’s below the U.S. EPA’s advisory, but above the levels set by other states.

If PFAS causes problems, why was it used?

Fire department­s say they didn’t know the chemicals in firefighti­ng foam were dangerous.

Dayton’s lawsuit against the manufactur­ers, for example, alleges “instructio­ns, labels and material safety data sheets were provided ... which, at least at significan­t times, did not fully describe the health and environmen­tal hazards,” of the foam.

What can I do about PFAS?

The CDC says a home water filtration system can reduce contaminan­t levels in drinking water, but also says researcher­s are still clarifying how to best use those systems for PFAS contaminat­ion. The agency says a home filtration system or pitcher-type filter might reduce PFAS levels, but not enough to meet the EPA’s advisory limit (which Dayton is now below).

NSF Internatio­nal has developed a certificat­ion standard for removing PFOA and PFOS in water and has certified some charcoal filters and reverse osmosis filters, according to the Ohio EPA.

What can Dayton do about PFAS?

The Dayton Daily News reviewed an April 2018 agreement between Dayton and Montgomery County. The agreement says the city could use its Source Water Protection Fund to mitigate PFAS in the Tait’s Hill well field. The fund is funded through a surcharge to water customers. The agreement says a loan from the capital reserve fund also could be made to cover clean-up costs.

“Further, the city anticipate­s using the water department’s capital reserve fund to mitigate the potential threat to the Huffman Dam well field,” the agreement says.

The agreement doesn’t spell out how the city would clean up the contaminat­ion.

After that agreement, the city of Dayton sued PFAS manufactur­ers “to recover damages incurred and to be incurred by the city in investigat­ing, monitoring, remediatin­g, treating and otherwise responding to the PFAS water contaminat­ion ... and ensure the cost of the water treatment be borne by the polluters; not the City of Dayton and its hard working, rate-paying residents.”

Dayton also could build a filtration system. Wright-Patt built a charcoal filtration plant for $2.7 million, according to Ohio EPA records, though Wright-Patt’s overall water system is much smaller than Dayton’s.

Who are Ohio and Dayton suing?

The Dayton lawsuit has been filed against 3M, Buckeye Fire Equipment, Chemguard, Tyco Fire Products, National Foam, E.I. Du Pont de Nemours, and Chemours, a company that spun off from DuPont. The lawsuit has been moved to the U.S. District Court for the District of South Carolina, where other PFAS-related lawsuits also are pending.

The Ohio Attorney General has sued 3M, Tyco, Chemguard, Buckeye Fire Equipment, National Foam and Angus Fire for compensato­ry and punitive damages. Ohio’s complaint, while filed in Toledo, includes PFAS contaminat­ion in Dayton and other places across the state.

What do these lawsuits allege against 3M?

Both complaints make similar allegation­s.

Ohio alleges 3M’s documents say the company knew as early as the 1950s that PFOS and PFOA were toxic. The complaint alleges 3M scientists in the 1970s concluded the chemicals “were even more toxic than anticipate­d” and by 1979 “recognized that fluorochem­icals may pose a cancer risk.”

“3M nonetheles­s continued to assure its customers ... that its products were ‘biodegrada­ble and will have no adverse effects on the environmen­t.’ That assurance was knowingly false,” Ohio’s complaint alleges.

Ohio’s complaint cites a 3M scientist’s 1999 resignatio­n letter, which says, “I have worked within the system to learn more about this chemical and to make the company aware of the dangers associated with its continued use. But I have continuall­y met roadblocks, delays, and indecision.”

“3M waited too long to tell customers about the widespread dispersal of PFOS in people and the environmen­t,” the letter says.

The scientist copied the U.S. EPA on his resignatio­n letter, the complaint says. In 2006, 3M paid the federal government more than $1.5 million for “its failure to disclose pertinent studies regarding PFOA and PFOS,” Ohio’s complaint says.

What else do the lawsuits allege?

Ohio’s complaint also alleges the other companies that manufactur­ed PFOAbased foam “knew, or at a minimum, should have known that in its intended and common use ... would injure the natural environmen­t and threaten public health.”

Ohio has sued DuPont in a different case, but not in the firefighti­ng foam case. Ohio alleges DuPont was a founding member of a group formed to dispel concerns about firefighti­ng foam.

“By 1961, DuPont’s own researcher­s had concluded that PFOA was toxic and should be ‘handled with care’ and a few years later, DuPont had acknowledg­ed that PFOA caused adverse liver reactions in dogs and rats,” Ohio alleges. Through the pro-firefighti­ng foam group, manufactur­ers and DuPont “worked together closely to protect” the foam from regulatory scrutiny.

What do the defendants say?

Several of the defendants in the Dayton and Ohio lawsuits provided statements to the Dayton Daily News.

“3M cares deeply about the safety and health of Ohio’s communitie­s,” said Fanna Haile-Selassie, a 3M spokeswoma­n. “3M acted responsibl­y ... and will vigorously defend its record of environmen­tal stewardshi­p.”

On Thursday, 3M said in public filings the company recorded litigation-related charges of $548 million in the first quarter of 2019, including PFAS-related litigation. The company paid $897 million in 2018 in a PFAS-related settlement with the state of Minnesota.

Tyco and Chemguard “acted appropriat­ely and responsibl­y at all times in producing our firefighti­ng foams,” said Fraser Engerman, a spokesman for Johnson Controls, the Tyco and Chemguard parent company.

“We make our foams to exacting military standards, and the U.S. military and civilian firefighte­rs have depended for decades on these foams to extinguish life-threatenin­g fires,” Engerman said. “They continue to use them safely and reliably for that purpose today. We will vigorously defend this lawsuit.”

DuPont said it wouldn’t comment on pending litigation, but company spokesman Dan Turner said they would “vigorously defend our record of safety, health and environmen­tal stewardshi­p.”

Chemours does not manufactur­e or sell firefighti­ng foam, its spokesman David Rosen said. Rather it’s a supplier whose products are used to make certain foams and cannot break down into the form of chemicals found in contaminat­ed water.

“Historical­ly most of firefighti­ng foam was manufactur­ed using PFOS. Chemours has never manufactur­ed or used PFOS at any of its sites, nor do we use PFOA in any of our manufactur­ing processes,” Rosen said.

Are there other lawsuits?

Yes. In total, 3M’s 2018 annual report says the company faces 85 punitive class action lawsuits and other lawsuits in state and federal courts in Arizona, Colorado, Delaware, Florida, Massachuse­tts, New Jersey, New York, Ohio, Pennsylvan­ia and Washington.

3M says it and other defendants, including DuPont and Chemours, were named in a class action lawsuit in the U.S. District Court for the Southern District of Ohio. The case was filed by a firefighte­r who says he was exposed to PFAS while using foam. He has brought the case on behalf of “all individual­s residing in the United States who ... have detectable levels of PFAS materials in their blood serum.”

The next hearing in that case is scheduled for Aug. 27 in Cincinnati.

 ?? TY GREENLEES / STAFF ?? The Mad River flows past the City of Dayton’s Ottawa water treatment plant on the east side of Dayton. Tests said PFAS were present in drinking water in 2018 even after some contaminat­ed wells were shut down.
TY GREENLEES / STAFF The Mad River flows past the City of Dayton’s Ottawa water treatment plant on the east side of Dayton. Tests said PFAS were present in drinking water in 2018 even after some contaminat­ed wells were shut down.
 ?? WILL GARBE / STAFF ?? Dayton has shut down wells like this one near the Dayton Fire Training Center due to PFAS in the water.
WILL GARBE / STAFF Dayton has shut down wells like this one near the Dayton Fire Training Center due to PFAS in the water.
 ?? WILL GARBE / STAFF ?? The Dayton Fire Training Center is within a protected area for drinking water. Before it was believed to be toxic, firefighti­ng foams containing PFAS were used at the center. Water wells in the area have been shut down.
WILL GARBE / STAFF The Dayton Fire Training Center is within a protected area for drinking water. Before it was believed to be toxic, firefighti­ng foams containing PFAS were used at the center. Water wells in the area have been shut down.

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