Rover finds organic molecules on Mars
Over nearly six years roaming the surface of Mars, NASA’s Curiosity rover has detected organic molecules that offer a taste of what an ancient life-friendly red planet might have looked like. Now, the rover’s pulled together a veritable feast.
The discovery of a wide variety of organic molecules and the detection of a seasonal methane pattern — described in two separate studies in the journal Science — add new fuel to the search for past life on Mars, scientists said.
“Both these finding(s) are breakthroughs in astrobiology,” Inge Loes ten Kate of Utrecht University, who was not involved in either study, wrote in a commentary on the paper.
Ever since the twin Viking landers touched down in 1976, scientists have hunted for signs of organic molecules on Mars. At their most basic, organic molecules are those made of carbon and hydrogen atoms, though they can have other atoms (such as oxygen or sulfur) as well. They can come from living and nonliving sources, but because many are necessary for and produced by life on Earth, they’re considered possible biosignatures — signs of the presence of life.
Curiosity, which has been exploring Gale Crater since it landed in 2012, has previously dug up signs of organic molecules in the ancient lake bed by taking rock samples and subjecting them to the suite of laboratory instruments in its belly. The problem was that these organic molecules contained an unusual atom: chlorine.
“The thing about the chlorinated molecules is that it’s not what you’d typically find in natural samples, and so we weren’t sure what the significance was at the time,” Jennifer Eigenbrode of NASA’s Goddard Space Flight Center in Maryland, lead author of one of the papers, said in a briefing. “However, it did give us a lot of motivation to keep looking.”
So the rover was directed to drive about four miles to the base of Mount Sharp, the 3-mile-high mound in the middle of Gale Crater whose layers of sediments serve as individual chapters in the geological history of Mars. Samples were drawn from two locations, Mojave and Confidence hills, and subjected to Curiosity’s Sample Analysis at Mars instrument suite.
For the previous mud stone samples that had produced the chlorinated molecules, scientists had heated the powdered rock to 200 degrees Celsius. But for this sample, Eigenbrode and her colleagues analyzed only the gases that were released above 400 degrees Celsius.
At that temperature, “they can be certain that these gases are not a result of leaking reagent or reaction with perchlorate,” ten Kate wrote.
The results revealed a wealth of organics, Eigenbrode said — including some that had carbons linked in ring structures (such as benzenes) and others that include carbon chains (such as propane).
“Because we see these coming off of the sample at high temperatures, what they’re really telling us is that they’re part of something larger, a macromolecule,” she said.
Such a macromolecule might potentially look something like kerogen, Eigenbrode said — a substance that’s found in coal and black shale and meteorites. On Earth, it’s often the result of ancient plant or microbial matter.
These organic molecules had managed to survive in rock that was about 3.5 billion years old, and that may have lain within a few centimeters of the surface for perhaps 100,000 years, Eigenbrode said.
That may be because many of the compounds, such as thiophene, methanethiol and dimethyl sulfide, had sulfur atoms in their molecular structure — which would strengthen the relatively fragile organic molecules, allowing them to survive the radiation bombarding the planet’s surface for so long.
“There were a lot of people who thought we weren’t going to find all the organic molecules that we did,” Eigenbrode said. With this new, diverse set of molecules, “we can now start to understand a little bit more about how this material is preserved and where else we might look to get more.”
The second paper, led by Christopher Webster of the Jet Propulsion Laboratory in La Canada Flintridge marks a major step toward solving the mystery of methane on Mars. Methane is one of those key organic molecules that on Earth are largely produced by living things, and can also be eaten by them, and so could theoretically serve as a signal of the possibility or presence of life. But methane can also be produced by normal geologic processes.
The first step to figuring out whether a methane signal is biological is to determine where it’s coming from. On Mars, that’s been a maddening challenge: Though scientists have detected bursts of methane on the planet, they’ve appeared at random — and thus it’s been difficult to figure out what the source is.
Now, with years of Curiosity’s atmospheric readings at their disposal, Webster and his colleagues were able to analyze 55 Earth months (roughly three Martian years) of data, finding that there were indeed low levels of background radiation — and that it seemed to experience seasonal surges, nearly tripling at its peak near summer’s end in the northern hemisphere (and winter’s end in the south).
This seasonal pattern seems to imply that temperature changes might be triggering the seasonal release, the scientists said, suggesting that the methane might be stored in water-based crystals called clathrates.