Los Angeles Times

Material has strength in fibers

- AMINA KHAN

Move over, Styrofoam. Scientists have designed a heat-insulating material made from wood that is both light and strong and made entirely from tiny, strippeddo­wn wood fibers.

So-called nanowood, described in the journal Science Advances, could one day be used to make more energy-efficient buildings. It’s cheap and biodegrada­ble too.

“Nature is producing this kind of material,” said senior author Liangbing Hu, a materials scientist and engineer at the University of Maryland in College Park.

Managing heat is a major issue in the cities we build. It’s hard to keep heat indoors in the winter and outdoors in the summer. The insulating materials in use are often very expensive to make, both in terms of money and energy. They’re not usually biodegrada­ble and ultimately contribute to our landfills. So scientists have been trying to come up with cheaper, more environmen­tally friendly options.

Hu has been studying the properties of nanocellul­ose, nanometer-scale versions of cellulose, the tough carbohydra­te in the cell walls of plants that allows tree trunks to grow strong and tall. At these incredibly small scales, cellulose fibers can take on remarkable characteri­stics, including a strength-to-weight ratio that’s about eight times that of steel.

Hu and his team have already developed a strong, dense material they called super wood, in part by removing some of the wood’s lignin — a complex polymer that holds cellulose in the wood together, almost like glue — and hemicellul­ose, another component of woody tissue.

But for this project, Hu and his colleagues removed all of the lignin and most of the hemicellul­ose. Lignin is very good at conducting heat — which means it would be a terrible insulator. Without all that lignin, the woody material turned pure white, allowing it to reflect incoming light rather than absorb it (which also helps to block heat).

The secret to nanowood’s insulating powers lies partly in its structure. Styrofoam is isotropic: It basically looks the same from any angle. t Nanowood is anisotropi­c: The fibers are bundled together in parallel, so it looks very different from different angles. Heat can travel up and down the fibers with ease, but can’t easily cross them, particular­ly because of the air gaps left after all the woody filler (lignin and hemicellul­ose) is removed.

The scientists found that nanowood was just as good an insulator as Styrofoam — better, even. It far outclassed other materials too.

“When exposed to the solar spectrum, the silica aerogel absorbs ~20% and transmits ~60% of the radiative heat,” the study authors wrote. “In comparison, ~95% of the radiative energy was reflected, whereas only ~2% was found absorbed by the nanowood.”

On top of that, the nanowood was also lightweigh­t and could withstand pressures of 13 megapascal­s. That’s about 50 times higher than insulators like cellulose foam and more than 30 times higher than the strongest of the commercial­ly used thermal insulation materials, they said.

“To the best of our knowledge, the strength of our nanowood represents the highest value among available super insulating materials,” the study authors wrote.

Even better, nanocellul­ose is readily available and relatively cheap to process, potentiall­y costing as little as $7.44 per square meter. (The key to keeping it sustainabl­e, Hu added, would be to harvest fast-growing trees such as balsa and leave slow-growing trees alone.) In the right conditions, bacteria can eat it, making it biodegrada­ble.

“When the thickness is less than 1 mm, the nanowood slice can be rolled and folded, making it suitable for scenarios that require flexibilit­y, such as pipelines in chemical factories and power plants,” the authors wrote.

Hu said that such a strong, lightweigh­t, thermally insulating biodegrada­ble material could have a host of uses. It could help build skyscraper­s, manufactur­e cars and even protect heat-sensitive electronic­s, on Earth or in space.

amina.khan@latimes.com

 ?? Hua Xie University of Maryland ?? SO-CALLED nanowood is a heat-insulating material made from wood that is both light and strong.
Hua Xie University of Maryland SO-CALLED nanowood is a heat-insulating material made from wood that is both light and strong.

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