Marin Independent Journal

3 scientists win Nobel in chemistry for research into quantum dots

- By David Keyton, Christina Larson and Rodrique Ngowi

Three scientists won the Nobel Prize in chemistry Wednesday for their work on quantum dots — tiny particles just a few nanometers in diameter that can release very bright colored light and whose applicatio­ns in everyday life include electronic­s and medical imaging.

Moungi Bawendi of MIT, Louis Brus of Columbia University, and Alexei Ekimov of Nanocrysta­ls Technology Inc., were honored for their work with the tiny particles that “have unique properties and now spread their light from television screens and LED lamps,” according to the Royal Swedish Academy of Sciences, which announced the award in Stockholm.

The suspense surroundin­g the academy's decision took an unusual turn when Swedish media reported the winners several hours before the prize was announced. The advance notice apparently came from a news release sent out early by mistake.

Quantum dots are tiny inorganic particles that glow a range of colors from red to blue when exposed to light. The color they emit depends upon the size of the particle.

Scientists can engineer the dots from materials that include gold to graphene to cadmium, and create their color by controllin­g their size. The tiniest particles, in which electrons are most tightly confined, emit blue light. Slightly larger particles, in which electrons bounce around a longer wavelength, emit red light.

Chemists sometimes compare the size of the particle itself to a confining box.

The underlying “particle in a box” theory of quantum

mechanics was first described nearly a century ago. But it wasn't until several decades later that scientists could manufactur­e quantum dots in a lab.

In the 1980s, Ekimov, 78, and Brus, 80, honed the theory and developed early laboratory techniques for creating particles that emit varying colors by adjusting sizes. In 1993, Bawendi, 62, developed new chemical methods for producing the particles quickly and uniformly — which soon enabled a variety of scalable commercial applicatio­ns, including in electronic­s displays.

Judy Giordan, president of the American Chemical Society, said she was thrilled at this year's winners.

“What we care about a lot in chemistry is being able to make and tailor novel structures and architectu­res to solve problems that help people and the planet,” Giordan said.

Rigoberto Advincula, a materials chemist at Oak Ridge National Laboratory in Tennessee, said the work helped bridge the fields of physics and chemistry, adding: “This technology is very easy to reproduce — that's why it became so popular and so widespread.”

Today quantum dots are

commonly used in electronic­s displays and biomedical imaging. The florescent quality of the particles allows researcher­s to track how drugs are delivered within the human body, as well as to study the precise location and growth of a tumor, for example.

Swedish media reported hours before Wednesday's announceme­nt that the Royal Swedish Academy of Sciences had sent out a news release that identified Bawendi, Brus and Ekimov as the latest Nobel laureates.

Public broadcaste­r SVT said the release said they were receiving the prize for the “discovery and synthesis of quantum dots.”

After officially announcing the three winners, Secretary-General Hans Ellegren said the Swedish academy would investigat­e how the informatio­n got out in advance.

“There was a press release sent out for still unknown reasons. We have been very active this morning to find out exactly what happened,” he said. “This is very unfortunat­e and we deeply regret what happened.”

The academy, which awards the physics, chemistry and economics prizes, asks for nomination­s

a year in advance from thousands of university professors and other scholars around the world.

A committee for each prize then discusses candidates in a series of meetings before presenting one or more proposals to the full academy for a vote. The deliberati­ons, including the names of nominees other than the winners, are kept confidenti­al for 50 years.

Bawendi told the news conference he was “very surprised, sleepy, shocked, unexpected and very honored.”

Asked about the leak, he said he didn't know he'd been made a Nobel laureate until he was called by the academy.

Bawendi said he was not thinking about the possible applicatio­ns of his work when he started researchin­g quantum dots.

“The motivation really is the basic science. A basic understand­ing, the curiosity of how does the world work? And that's what drives scientists and academic scientists to do what they do,” he said.

Brus, a professor emeritus at Columbia, said he didn't pick up the phone when the early morning call came from the Swedish academy to notify him.

 ?? THE ASSOCIATED PRESS ?? This combo image shows Professor Emeritus Louis Brus, left, Alexei Ekimov of Nanocrysta­ls Technology Inc., center, and Massachuse­tts Institute of Technology scientist Moungi Bawendi. The three scientists in the United States won the Nobel Prize in chemistry for their work on quantum dots.
THE ASSOCIATED PRESS This combo image shows Professor Emeritus Louis Brus, left, Alexei Ekimov of Nanocrysta­ls Technology Inc., center, and Massachuse­tts Institute of Technology scientist Moungi Bawendi. The three scientists in the United States won the Nobel Prize in chemistry for their work on quantum dots.

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