San Francisco Chronicle

Could beach pebbles help solve climate change?

- By Peter Fimrite

Of all the ideas that circulated during the recent American Geophysica­l Union meeting at the Moscone Center, one of the most outlandish­sounding schemes was from a San Francisco entreprene­ur who claims he can help conquer climate change by sprinkling pebbles on tropical beaches.

The proposal appears, to the uninitiate­d, to be a firstclass boondoggle, but California’s top climate scientists not only support the notion that rocks can sequester carbon, they are clamoring for viable experiment­s to test the theory.

Eric Matzner, who founded the nonprofit Project Vesta this year, intends to mine tons of a soft, crumbly green volcanic stone called olivine, grind it into pebbles and spread it on shorelines, coves and beaches, where the wave action will weather it down like a river sculpts gravel.

Scientists say the process of erosion chemically alters the acidic molecules in seawater and converts carbon dioxide into bicarbonat­e, thereby taking the heattrappi­ng gases out of circulatio­n and reversing acidificat­ion, one of the primary concerns of global warming. The more the rock breaks down, the more carbon dioxide is taken out of the sea.

It is a natural process that is believed to occur faster in the

tropics, where warmer temperatur­es help the dissolutio­n process. That explains Matzner’s desire to do a trial run there.

Scientists say the periodic exposure to the elements of big chunks of volcanic rock as a result of tectonic movement has, over a geologic time scale, influenced the Earth’s climate, even helping bring on ice ages.

That’s because volcanic rocks are alkaline and react to the carbon dioxide in the atmosphere. Scientists have found that grinding the rocks, like the surf does, increases the reactive surface area of the particles, stimulatin­g consumptio­n of CO2.

What Matzner and his partner, Francesc Montserrat, a marine ecologist in the Netherland­s, want to do is speed up the natural process by doing what climate scientists call “enhanced weathering,” essentiall­y rubbing off the oxidation layer built up over time that prevents the molecules from reacting.

“We’re intervenin­g,” Matzner said. “We’re accelerati­ng Earth’s natural process of carbon renewal. In the grand scheme of things, we are putting the carbon in the atmosphere back into rock.”

The plan is to raise $1 million to $1.5 million and use it to collect the stone, grind it into pebbles and pour it on a shoreline, creating an olivine beach. The pilot program would determine the least expensive, most energyeffi­cient way to accomplish the task, including mining, transport and distributi­on. The research would compare the amount of carbon dioxide removed to how much is produced by the process.

The two men, who have so far raised about $100,000, chose olivine, which is made of magnesium and silica, because “it’s the fastest weathering silicate,” Matzner said. The gemstone, commonly known as peridot, the August birthstone, is also extremely abundant. It is often found in the tailings left over from the mining of diamonds and other minerals.

“There is enough olivine to remove all human emissions, ever,” Matzner said. “We think this is a viable method to remove CO2 on a large scale.”

According to a special report by the U.N. Intergover­nmental Panel on Climate Change released in September, more than 90% of the heat and 20% to 30% of the carbon dioxide from cars and factories is absorbed by the ocean. This causes the water to lose oxygen and become more acidic, which has devastatin­g consequenc­es for marine life.

Montserrat, a senior environmen­tal engineer at a dredging company in the Netherland­s, said he has been studying ways to recapture carbon since 2011.

He and a colleague conducted experiment­s in 2016 on Papakolea Beach, a natural olivine beach famous for its green sand, on the Big Island of Hawaii, and published two papers analyzing the enhanced weathering process.

Matzner recruited Montserrat for his project after reading his report.

“It’s buying time,” Montserrat said. “You need to cut carbon emissions, but every year we don’t cut emissions it becomes more clear that we need to find a way to remove CO2.”

Project Vesta is the first to propose using ocean waves to weather volcanic rocks, but it isn’t the first organizati­on to study how rock sequesters carbon.

The idea was mentioned in the 2016 Paris climate agreement, a pledge by nearly 200 nations to cut emissions and prevent global temperatur­es from rising more than 3.6 degrees Fahrenheit above average preindustr­ial levels, the point at which warming could begin to have catastroph­ic consequenc­es. President Trump plans to withdraw the United States from the Paris agreement in 2020.

Studies using crushed volcanic rock on crops have been conducted in the Midwest, Australia, Malaysia and the United Kingdom. In California, UC Davis researcher­s started field experiment­s this year with pulverized volcanic rock on 100 acres of alfalfa, corn and almond crops and on rangeland across the Central Valley.

Project leader Ben Houlton, director of the John Muir Institute of the environmen­t at UC Davis, said the study — funded with $5 million from California’s capandtrad­e program — uses a metabasalt taken from the tailings at a local mine and subjects it to the same weathering process as the beach project would, except on land.

Houlton said olivine was ruled out because it would poison the soil with heavy metals. The rock he uses was selected because it has potassium and zinc in it, which is good for crops. It is pulverized and mixed with the topsoil, where microbial activity causes the weathering that allows carbon dioxide to be consumed.

The idea, Houlton said, is to make the process healthful for crops and useful economical­ly — crop yields have gone up 15% to 20% using the material — providing an incentive for sequesteri­ng carbon.

Houlton said his models have shown that farmers could capture between 5 and 10 billion tons of CO2 per year — a little less than a third of what is emitted worldwide — if 75% of earth’s croplands were treated this way.

“I think the capacity for a global scale solution is there,” he said, “but there is still a lot of progress to make on the science that is needed to validate this approach.”

The questions are how fast it can be scaled up, how much it would cost and whether scaling up the process would produce more carbon than it would remove. Also, nobody knows what effect leaching metals, like nickel, would have on the marine environmen­t as olivine dissolves.

“In the bigpicture sense, we know that the formation of carbonate rocks is one of the main ways that nature provides longterm removal of atmospheri­c CO2,” said Christophe­r Field, a climate scientist at the Stanford Woods Institute for the Environmen­t. “One challenge is getting a process that operates in nature on geological time scales (millions of years) to operate much more quickly. The second challenge is getting the accelerati­on without requiring so much energy input that we dig a hole we can’t get out of.”

Matzner believes olivine beaches could be turned into economic and cultural resources if government­s begin using the substance to fix eroded coastlines or replace sand washed away by rising tides.

“That would be a great way to get lots of this sand deployed,” he said, adding that he will be pushing olivine wedding rings and other jewelry in the name of helping Mother Nature. “We want to create a movement.”

 ?? Marco Garcia / Associated Press 2014 ?? Sunbathers visit Papakolea beach on the Big Island of Hawaii. The green sand is made of olivine, a substance that removes carbon dioxide from seawater.
Marco Garcia / Associated Press 2014 Sunbathers visit Papakolea beach on the Big Island of Hawaii. The green sand is made of olivine, a substance that removes carbon dioxide from seawater.
 ?? Marco Garcia / Associated Press 2014 ?? The green sand of Papakolea beach in Hawaii is made of olivine, a volcanic rock that removes carbon dioxide from seawater.
Marco Garcia / Associated Press 2014 The green sand of Papakolea beach in Hawaii is made of olivine, a volcanic rock that removes carbon dioxide from seawater.

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