The Mercury News

Black smoke, flames shoot up from Texas chemical plant

- By Frank Bajak and Reese Dunklin

Thick black smoke and towering orange flames shot up Friday from a flooded Houston-area chemical plant after two trailers of highly unstable compounds blew up a day earlier after losing refrigerat­ion.

It was the second day that flames and smoke could be seen at the Arkema plant in Crosby. Arkema says Harvey’s floodwater­s engulfed its backup generators and knocked out the refrigerat­ion necessary to keep the organic peroxides from degrading and catching fire. Arkema executive Richard Rennard said two containers caught fire Friday evening, and that the company has six more that it expects will eventually catch fire.

The Environmen­tal Protection Agency and local officials said an analysis of the smoke that came from the plant early Thursday showed no reason for alarm. No serious injuries were reported. EPA spokesman David Gray said the agency was sending its surveillan­ce aircraft through the area again Friday night to monitor any airborne toxic chemicals and “will have informatio­n shortly.”

A 1½ mile buffer around the plant was establishe­d Tuesday when Arkema Inc. warned that chemicals kept there could explode. Employees had been pulled, and up to 5,000 people living nearby were warned to evacuate. Officials remain comfortabl­e with the size of the buffer, Rachel Moreno, a spokeswoma­n for the Harris County Fire Marshal Office, said Friday evening.

Arkema spokeswoma­n Janet Smith reiterated statements executives made earlier Friday that the safest course of action is to simply “let these fires happen and let them burn out.”

Harvey’s floodwater­s engulfed backup generators and cut off the refrigerat­ion necessary to keep the organic peroxides, used in such products as plastics and paints, from degrading and catching fire.

Arkema officials did not directly notify local emergency managers of the generator failure, Moreno said.

In a conference call with reporters Friday, Arkema President and CEO Rich Rowe apologized and said he was sending a team of employees to Crosby to figure out how best to assist locals.

“I realize this is not a situation that we can help remedy overnight,” he said.

Early Thursday, two blasts blew open a trailer containing at least 2 tons of material, sending up a plume of black smoke and flames 30- to 40-foot high in the tiny town of Crosby, about a half-hour from Houston, authoritie­s said. The Texas environmen­tal agency called the smoke “especially acrid and irritating” and said it can impair breathing and inflame the eyes, nose and throat.

Questions persisted Friday about the adequacy of Arkema’s master plan to protect the public in the event of an emergency in flood-prone Houston, a metropolit­an area of about 6 million people.

The plant is along a corridor with one of the nation’s greatest concentrat­ions of refineries, pipelines and chemical plants. A 2016 analysis led by Texas A&M University researcher­s identified Arkema’s facility as posing one of the region’s biggest risks, based on such factors as the type and amount of chemicals and the population density.

“This should be a wakeup call (for) all kinds of plants that are storing and converting reactive chemicals in areas which have high population densities,” said Massachuse­tts Institute of Technology expert Nicholas Ashford.

In accident plans Arkema submitted to the Environmen­tal Protection Agency in 2014, executives said a hurricane and a power loss were potential hazards. Yet the plans, which were supposed to address worst-case scenarios, didn’t explain what Arkema would do if faced with either.

Executives also acknowledg­ed Friday that they didn’t have materials at the plant that could have neutralize­d the organic peroxides.

Instead, workers were forced to scramble and move the chemicals away from floodwater­s after buildings were engulfed and power was lost. Workers transferre­d the compounds to refrigerat­ed containers, but those failed, too, causing Thursday’s fire.

Arkema officials had not directly notified local emergency managers of the generator failure, said Moreno. The plant’s workers told the Crosby Volunteer Fire Department about it when they were rescued during the storm, she said.

Despite receding waters, Arkema vice president Daryl Roberts said he didn’t think refrigerat­ion systems would restart, but the organic peroxides were a safe distance from other hazardous chemicals.

After days of questions about what was in its chemical inventory, the company posted a list of them on its website Friday, though not the amounts on hand. Asked why it hadn’t shared the informatio­n sooner, Rowe said, “We’re managing our way through a crisis.”

State and federal regulators have cited Arkema for safety and environmen­tal violations at the Crosby plant dating back more than a decade, records show.

Texas’ environmen­tal commission penalized the plant at least three times. In June 2006, Arkema had failed to prevent unauthoriz­ed emissions during a two-hour warehouse fire. Records show a pallet of organic peroxide was poorly stored, resulting in the blaze, and more than a ton of volatile organic compounds were discharged.

More recently, the U.S. Occupation­al Safety and Health Administra­tion in February fined Arkema nearly $110,000 — later reduced to just over $90,000 — because of 10 serious safety violations found during an inspection.

“We don’t have a perfect record, we understand that,” Arkema’s Rowe said. “We strive to get better at every turn and will continue to do so.”

 ?? THE ASSOCIATED PRESS ?? Thick black smoke and towering orange flames shot up Friday from the flooded Houstonare­a chemical plant after two trailers of highly unstable compounds blew up a day earlier after losing refrigerat­ion.
THE ASSOCIATED PRESS Thick black smoke and towering orange flames shot up Friday from the flooded Houstonare­a chemical plant after two trailers of highly unstable compounds blew up a day earlier after losing refrigerat­ion.

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